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A novel pillar-layered Mn–organic framework constructed from 1D S-shaped chains and flexible tricarboxylate ligands for wide-range temperature sensing

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Abstract

In this work, by using a flexible tricarboxylate ligand 5-(4-carboxybenzyloxy) isophthalic acid (H3L), a novel pillar-layered Mn–organic framework, namely, [(CH3CH2)2NH2][Mn3(HL)L(AC)2] (SQNU-23, SQNU = Shangqiu Normal University), was synthesized by using a DEF/HAc solvent system. In SQNU-23, each S-shaped Mn-O chain is interconnected by two bridging modes of organic ligand to form a 3D pillar-layered framework with 1D rectangular channels. The solid-state fluorescence of SQNU-23 exhibits a significant red shift of about 140 nm compared to that of organic ligand. Moreover, SQNU-23 as a luminescent thermometer exhibits good linear dependence in the wide temperature range (100 to 300 K).

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Data availability

The SQNU-23.CIF files are available in the Cambridge Structural Database (CSD) and the CCDC number is 2368286.

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Funding

This work was supported by the National Natural Science Foundation of China (52472222 and 22301172) and the Science and Technology Innovation Talents in Universities of Henan Province (22HASTIT028).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo, 454000, PR China

    Xi Li, Xian-Lei Shi & Wei Wei

  2. School of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu, 476000, PR China

    Jian-Wei Zhang, Xin-Cheng Hu & Wei Wei

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  1. Xi Li
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  2. Jian-Wei Zhang
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  3. Xin-Cheng Hu
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  4. Xian-Lei Shi
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  5. Wei Wei
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Contributions

X.L. contributes for the TGA and PXRD tests. J.-w.Z. contribute for the main manuscript. X.-c.H. contribute for the figures. X.-l. S. and W.W. contributes for the conception of this manuscript. All authors reviewed the manuscript.

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Correspondence to Jian-Wei Zhang or Wei Wei.

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Li, X., Zhang, JW., Hu, XC. et al. A novel pillar-layered Mn–organic framework constructed from 1D S-shaped chains and flexible tricarboxylate ligands for wide-range temperature sensing. Struct Chem 36, 983–988 (2025). https://doi.org/10.1007/s11224-024-02425-y

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  • DOI: https://doi.org/10.1007/s11224-024-02425-y

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