Polonium
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| Polonium | ||||||||||||||||||||||||||||||
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| Pronunciation | /pəˈloʊniəm/ (ⓘ) | |||||||||||||||||||||||||||||
| Allotropes | α, β | |||||||||||||||||||||||||||||
| Appearance | silvery | |||||||||||||||||||||||||||||
| Mass number | [209] | |||||||||||||||||||||||||||||
| Polonium in the periodic table | ||||||||||||||||||||||||||||||
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| Atomic number (Z) | 84 | |||||||||||||||||||||||||||||
| Group | group 16 (chalcogens) | |||||||||||||||||||||||||||||
| Period | period 6 | |||||||||||||||||||||||||||||
| Block | p-block | |||||||||||||||||||||||||||||
| Electron configuration | [Xe] 4f14 5d10 6s2 6p4 | |||||||||||||||||||||||||||||
| Electrons per shell | 2, 8, 18, 32, 18, 6 | |||||||||||||||||||||||||||||
| Physical properties | ||||||||||||||||||||||||||||||
| Phase at STP | solid | |||||||||||||||||||||||||||||
| Melting point | 527 K (254 °C, 489 °F) | |||||||||||||||||||||||||||||
| Boiling point | 1235 K (962 °C, 1764 °F) | |||||||||||||||||||||||||||||
| Density (near r.t.) | α-Po: 9.196 g/cm3 β-Po: 9.398 g/cm3 | |||||||||||||||||||||||||||||
| Heat of fusion | ca. 13 kJ/mol | |||||||||||||||||||||||||||||
| Heat of vaporization | 102.91 kJ/mol | |||||||||||||||||||||||||||||
| Molar heat capacity | 26.4 J/(mol·K) | |||||||||||||||||||||||||||||
Vapor pressure
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| Atomic properties | ||||||||||||||||||||||||||||||
| Oxidation states | −2, +2, +4, +5,[1] +6 (an amphoteric oxide) | |||||||||||||||||||||||||||||
| Electronegativity | Pauling scale: 2.0 | |||||||||||||||||||||||||||||
| Ionization energies |
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| Atomic radius | empirical: 168 pm | |||||||||||||||||||||||||||||
| Covalent radius | 140±4 pm | |||||||||||||||||||||||||||||
| Van der Waals radius | 197 pm | |||||||||||||||||||||||||||||
| Other properties | ||||||||||||||||||||||||||||||
| Natural occurrence | from decay | |||||||||||||||||||||||||||||
| Crystal structure | cubic α-Po | |||||||||||||||||||||||||||||
| Crystal structure | rhombohedral β-Po | |||||||||||||||||||||||||||||
| Thermal expansion | 23.5 µm/(m⋅K) (at 25 °C) | |||||||||||||||||||||||||||||
| Thermal conductivity | 20 W/(m⋅K) (?) | |||||||||||||||||||||||||||||
| Electrical resistivity | α-Po: 0.40 µΩ⋅m (at 0 °C) | |||||||||||||||||||||||||||||
| Magnetic ordering | nonmagnetic | |||||||||||||||||||||||||||||
| CAS Number | 7440-08-6 | |||||||||||||||||||||||||||||
| History | ||||||||||||||||||||||||||||||
| Naming | after Polonia, Latin for Poland, homeland of Marie Curie | |||||||||||||||||||||||||||||
| Discovery | Pierre and Marie Curie (1898) | |||||||||||||||||||||||||||||
| First isolation | Willy Marckwald (1902) | |||||||||||||||||||||||||||||
| Isotopes of polonium | ||||||||||||||||||||||||||||||
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Polonium is a rare radioactive metalloid.[4] It is chemical element 84 on the periodic table and its symbol is Po. It was discovered in 1898 by Marie and Pierre Curie.
Polonium is highly unstable, radioactive and toxic. This makes it difficult to handle. It can be dangerous, even in very small amounts. One gram of Po will self-heat to a temperature of about 500 °C (932 °F). It also vaporizes easily.
Polonium has 42 isotopes, and all of them are radioactive. It is a very rare element in nature because of its short half-life. It is a breakdown product of uranium, so it is found in uranium ores.
Polonium is also very important because it is the main element of nuclear bombs.
Polonium emits alpha radiation, which cannot pass through the skin and is blocked by a piece of paper. [5][6]
Properties
[change | change source]Polonium emits alpha radiation, and it has a half-life of 138 days (approximately 4 months). It decays into Lead, A milligram of polonium emits about as many alpha particles per second as 5 grams of Radium, which means it is 5,000 times more radioactive than radium. A few grams of Polonium emit a blue glow which is caused by ionization of the surrounding air.[7] Polonium is 100 billion times more dangerous than hydrogen cyanide. [8][9]
Polonium has an atomic number of 84, meaning it has 84 protons, which is why it's so unstable, because it's atom is large. [10]
References
[change | change source]- ↑ Thayer, John S. (2010). "Relativistic Effects and the Chemistry of the Heavier Main Group Elements". Relativistic Methods for Chemists. Challenges and Advances in Computational Chemistry and Physics. 10: 78. doi:10.1007/978-1-4020-9975-5_2. ISBN 978-1-4020-9974-8.
{{cite journal}}: CS1 maint: periodical has ISBN (link) - ↑ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
- ↑ Boutin, Chad. "Polonium's Most Stable Isotope Gets Revised Half-Life Measurement". nist.gov. NIST Tech Beat. Retrieved 9 September 2014.
- ↑ "Characterizing the Elements". Los Alamos National Laboratory. Retrieved 4 March 2013.
- ↑ "Polonium - Element information, properties and uses | Periodic Table". periodic-table.rsc.org. Retrieved 2026-06-05.
- ↑ "Alpha Radiation | Physics | Research Starters | EBSCO Research". EBSCO. Retrieved 2026-06-05.
- ↑ "Polonium-210". Federal Office for Radiation Protection. Retrieved 2026-06-05.
- ↑ "Polonium (Po) | History | Research Starters | EBSCO Research". EBSCO. Retrieved 2026-06-05.
- ↑ Ansoborlo, Eric; Berard, Philippe; Den Auwer, Christophe; Leggett, Rich; Menetrier, Florence; Younes, Ali; Montavon, Gilles; Moisy, Philippe (2012-08-20). "Review of Chemical and Radiotoxicological Properties of Polonium for Internal Contamination Purposes". Chemical Research in Toxicology. 25 (8): 1551–1564. doi:10.1021/tx300072w. ISSN 0893-228X. PMID 22530998.
- ↑ "25.3: Stability of Atomic Nuclei". Chemistry LibreTexts. 2015-12-27. Retrieved 2026-06-05.
| H | He | ||||||||||||||||||||||||||||||||||||||||
| Li | Be | B | C | N | O | F | Ne | ||||||||||||||||||||||||||||||||||
| Na | Mg | Al | Si | P | S | Cl | Ar | ||||||||||||||||||||||||||||||||||
| K | Ca | Sc | Ti | V | Cr | Mn | Fe | Co | Ni | Cu | Zn | Ga | Ge | As | Se | Br | Kr | ||||||||||||||||||||||||
| Rb | Sr | Y | Zr | Nb | Mo | Tc | Ru | Rh | Pd | Ag | Cd | In | Sn | Sb | Te | I | Xe | ||||||||||||||||||||||||
| Cs | Ba | La | Ce | Pr | Nd | Pm | Sm | Eu | Gd | Tb | Dy | Ho | Er | Tm | Yb | Lu | Hf | Ta | W | Re | Os | Ir | Pt | Au | Hg | Tl | Pb | Bi | Po | At | Rn | ||||||||||
| Fr | Ra | Ac | Th | Pa | U | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | ||||||||||
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